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Anisotropic Molecular Organization at a Liquid/Vapor Interface Promotes Crystal Nucleation with Polymorph Selection

https://doi.org/10.1021/jacs.2c02623

Yao, Xin; Liu, Qitong; Wang, Bu; Yu, Junguang; Aristov, Michael M.; Shi, Chenyang; Zhang, Geoff G.; Yu, Lian (July 2022, Journal of the American Chemical Society)

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Effect of Polymers on Crystallization in Glass-Forming Molecular Liquids: Equal Suppression of Nucleation and Growth and Master Curve for Prediction

https://doi.org/10.1021/acs.cgd.9b01095

Yao, Xin; Huang, Chengbin; Benson, Emily G.; Shi, Chenyang; Zhang, Geoff G.; Yu, Lian (December 2019, Crystal Growth & Design)

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Crystal nucleation rates in glass-forming molecular liquids: D-sorbitol, D-arabitol, D-xylitol, and glycerol

https://doi.org/10.1063/1.5042112

Huang, Chengbin; Chen, Zhenxuan; Gui, Yue; Shi, Chenyang; Zhang, Geoff G.; Yu, Lian (August 2018, The Journal of Chemical Physics)

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Pair distribution functions of amorphous organic thin films from synchrotron X-ray scattering in transmission mode

https://doi.org/10.1107/s2052252517009344

Shi, Chenyang; Teerakapibal, Rattavut; Yu, Lian; Zhang, Geoff G. (September 2017, IUCrJ)

Using high-brilliance high-energy synchrotron X-ray radiation, for the first time the total scattering of a thin organic glass film deposited on a strongly scattering inorganic substrate has been measured in transmission mode. The organic thin film was composed of the weakly scattering pharmaceutical substance indomethacin in the amorphous state. The film was 130 µm thick atop a borosilicate glass substrate of equal thickness. The atomic pair distribution function derived from the thin-film measurement is in excellent agreement with that from bulk measurements. This ability to measure the total scattering of amorphous organic thin films in transmission will enable accurate in situ structural studies for a wide range of materials.
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